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Electrochemistry of organic sulfur compounds V. a polarographic study on the anodic oxidation of phenyl sulfides

โœ Scribed by Sigeru Torii; Kenji Uneyama; Kozo Iida; Kazuo Sasaki

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
192 KB
Volume
13
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

This paper describes a total analysis of polarograms in the oxidation of phenyl sulfides along uith a discussion based on complete products analysis, 3) since such electrochemical studies are required to establish a reliable theory on the mechanism of the anodic process. 4,5) Polarograms of sulfides (I, II, III, and IV) and the related products derived from the anodic oxidation ware measured in an acetonitrile solution of 0.2-0.3 mM of substrata containing 0.1 M of sodium perchlorate at 0 6) 20 .

The half-wave potentials on polarogrsms and the peak potentials in cyclic voltammetry are listed in Table I.

Typical polarograms of I, II, III, and

๐Ÿ“œ SIMILAR VOLUMES

Electrochemistry of organic sulfur compo
Electrochemistry of organic sulfur compounds II. Anodic sulfoxidation of Phenyl sulfides
โœ Kenji Uneyama; Sigeru Torii ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 191 KB

Anodic substitution of aromatic compounds is a subject of detailed investigations in recent years. 2) Many substituted aromatic compounds indicate that substitutions on aromatic nucleous and/or benzylic position are typical reaction pathways for the oxidation process. 2) But very few investigations