The Uethylxanthato and NJ'-dimethyldithiocarbamato main group metal complexes were produced by the one-step electrochemical oxidation of the metal (M = In, Sn, Pb, Bi, Te) in the presence of an acetone solution of ethyl dixanthogen or tetramethylthiuram disulphide.
✦ LIBER ✦
The electrochemical synthesis ofO-ethylxanthato- andN,N′-dimethyldithiocarbamato-complexes of oxovanadium(IV), manganese (III), zinc(II), silver(I) and cadmium(II)
✍ Scribed by Allan T. Casey; Angelica M. Vecchio
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 322 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0340-4285
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The metal-templated cyclocondensation of 2,6-diformylpyridine and 1,4-bis(2-aminophenoxy)butane in the presence of silver(I), zinc(II) and cadmium(II) salts gave the following di-imine macrocyclic complexes: 4) and [CdL(NO 3 )(CH 3 OH)](NO 3 ) (5) (L= macrocyclic ligand). All compounds have been cha