The electrochemical kinetics of the mercurous ion/mercury system in mixed solvents
β Scribed by P. Bindra; J. Ulstrup
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 506 KB
- Volume
- 140
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
Both elemental mercury and the mercurous ion give rise to a signal in Cold-Vapor Atomic Absorption Analysis under non-reducing conditions. Distinction between these species based on the greater solubility of the mercurous ion in water is possible, and the potential of this analytical distinction is
The analysis of polarographic and coulometric results shows that the overall reduction mechanism of chlorobenzenesulphonamide derivatives occurs with the cleavage of the C-Cl bond followed by the reduction of the benzenesulphonamide involving the S-N bond breaking. However, theg, ,2 values fit the s