Oxidation state analysis of mercury: Evidence of the formation of mercurous ion in the oxidation of mercury by peracetic acid
β Scribed by Donald C. Wigfield; Sherry L. Perkins
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 250 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0260-437X
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β¦ Synopsis
Both elemental mercury and the mercurous ion give rise to a signal in Cold-Vapor Atomic Absorption Analysis under non-reducing conditions. Distinction between these species based on the greater solubility of the mercurous ion in water is possible, and the potential of this analytical distinction is illustrated with the finding that oxidation of mercury by peracetic acid involves the mercurous state.
π SIMILAR VOLUMES
A general study of the anodic oxidation of mercury in the presence of ethane-1,2-bismercaptoacetic acid (ebma) is made by different polarographic techniques (dc,, dp and ac), cyclic voltammetry and coulometry at constant potential. The anodic process involves the reversible and diffusion-controlled
The anodic oxidation of mercury in the presence of 2.2'~thiobisacetic and 3,3'-thiobispmpanoic acids has been studied by dc,, dp, act and uc, polarography, cyclic voltammetry and coulometry. The electrode processes include the overall formation of the HgL$-complexes, through the dispropertionation o