The anodic chlorination of c-hexene in NM solution having 150 ppm water content involves three charge-transfer reactions. The effect of potential on change in product distribution is more effective at the beginning of electrolysis. A mechanism for the process is suggested.
The electrochemical bromination of c-hexene on a Pt electrode in nitromethane solution
✍ Scribed by Cs. Visy; M. Novák
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 226 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
In this process a complex intermediate forms between the olefin and Br2 evolved and it transforms to dibromo-c-hexane. At higher potential values theelectrochemical oxidation ofthiscomplex results bromoc-hexanol, the formation of which is hindered by oxide layer on the electrode surface.
📜 SIMILAR VOLUMES
Effect of water content on product dtstribution in electrochemical chlorination of c-hexene in nitromethane solution was studied. Formation of I-chloro, c-hexanone which occurs at the beginning of electrolysis is more effective at lower water content
and the path involving hydrogen peroxide suggested as [10]: