𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The electrochemical bromination of c-hexene on a Pt electrode in nitromethane solution

✍ Scribed by Cs. Visy; M. Novák


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
226 KB
Volume
32
Category
Article
ISSN
0013-4686

No coin nor oath required. For personal study only.

✦ Synopsis


In this process a complex intermediate forms between the olefin and Br2 evolved and it transforms to dibromo-c-hexane. At higher potential values theelectrochemical oxidation ofthiscomplex results bromoc-hexanol, the formation of which is hindered by oxide layer on the electrode surface.


📜 SIMILAR VOLUMES


Role of chloronium complex in the electr
✍ M. Novák; Cs. Visy 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 300 KB

The anodic chlorination of c-hexene in NM solution having 150 ppm water content involves three charge-transfer reactions. The effect of potential on change in product distribution is more effective at the beginning of electrolysis. A mechanism for the process is suggested.

Influence of water content on the produc
✍ M. Novák; Cs. Visy 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 198 KB

Effect of water content on product dtstribution in electrochemical chlorination of c-hexene in nitromethane solution was studied. Formation of I-chloro, c-hexanone which occurs at the beginning of electrolysis is more effective at lower water content