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Role of chloronium complex in the electrochemical chlorination of c-hexene in nitromethane

✍ Scribed by M. Novák; Cs. Visy


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
300 KB
Volume
28
Category
Article
ISSN
0013-4686

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✦ Synopsis


The anodic chlorination of c-hexene in NM solution having 150 ppm water content involves three charge-transfer reactions. The effect of potential on change in product distribution is more effective at the beginning of electrolysis. A mechanism for the process is suggested.


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Influence of water content on the produc
✍ M. Novák; Cs. Visy 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 198 KB

Effect of water content on product dtstribution in electrochemical chlorination of c-hexene in nitromethane solution was studied. Formation of I-chloro, c-hexanone which occurs at the beginning of electrolysis is more effective at lower water content

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