The overall proasses were determined for the reduction of Fe?\* to Fe", in an oxalate medium and at oxalate concentrations of less than 0.5M. The coordination numbers of the oxidized and reduced species were calculated, together with the number of intervening protons that depend on the oxalate conce
The electrochemical behavior of the Fe(II)-Fe(III) system in the presence of EDTA at pH 4.3
✍ Scribed by I. González; J.G. Ibaáñez; M.A. Cárdenas; A. Rojas-Hernández
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 386 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
Ah&act-The
objective of this work is to determine the type of mechanism that the Fe(III)-EDTA reduction follows on a flat Pt surface, at a pH which is representative of the most common pH range used for this system (3.5 < pH < 6.5). The techniques used are: LSV, CV, rde, rrde, and CP. The results show that the reduction of FeEDTA-follows an EC type mechanism forming a non-electroactive species first, which then reacts with the medium producing the electroactive species FeEDTA'-.
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