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The Elbs Peroxydisulfate Oxidation: Kinetics

✍ Scribed by Behrman, E. J.; Walker, Pamela P.


Book ID
124093697
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
453 KB
Volume
84
Category
Article
ISSN
0002-7863

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Semiempirical calculations show that the intermediate formed by reaction between peroxydisulfate anion and the phenolate ion (the Elbs oxidation) is the species resulting from reaction of the tautomeric carbanion rather than the one resulting from attack by the oxyanion. This is confirmed by synthes

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