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The Elbs and Boyland—Sims Peroxydisulfate Oxidations

✍ Scribed by E. J. Behrman


Book ID
102008384
Publisher
John Wiley and Sons
Year
2007
Weight
18 KB
Volume
38
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES


On the mechanism of the Elbs peroxydisul
✍ Elizabeth C. Behrman; Ssuhen Chen; Edward J. Behrman 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 65 KB

Semiempirical calculations show that the intermediate formed by reaction between peroxydisulfate anion and the phenolate ion (the Elbs oxidation) is the species resulting from reaction of the tautomeric carbanion rather than the one resulting from attack by the oxyanion. This is confirmed by synthes