The Efficient Stereoselective Synthesis of (Z)-Vinylsilanes Through the Suzuki-Miyaura Coupling of (Z)-(α-Silylvinyl)borinates. -Title reactions of air-stable borinates (I) with organic bromides (II) under standard basic conditions provide a stereoselective synthesis of (Z)-vinylsilanes (III), usef
✦ LIBER ✦
The efficient stereoselective synthesis of Z-vinylsilanes through the Suzuki-Miyaura coupling of Z-(α-silylvinyl)borinates
✍ Scribed by John A. Soderquist; Gisela León
- Book ID
- 104259322
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 128 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
, easily prepared in a hydroboration-ox~dn~_on sequence from I provide a particularly effective route to Z-vinylsilanes (3, 59-9796) through S~-Miyaura coupling.
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