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ChemInform Abstract: The Efficient Stereoselective Synthesis of (Z)-Vinylsilanes Through the Suzuki—Miyaura Coupling of (Z)-(α-Silylvinyl)borinates.

✍ Scribed by J. A. SODERQUIST; G. LEON

Book ID: 101865657
Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199834196

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✦ Synopsis

The Efficient Stereoselective Synthesis of (Z)-Vinylsilanes Through the Suzuki-Miyaura Coupling of (Z)-(α-Silylvinyl)borinates.

-Title reactions of air-stable borinates (I) with organic bromides (II) under standard basic conditions provide a stereoselective synthesis of (Z)-vinylsilanes (III), useful substrates for stereoselective conversions. -(SODERQUIST, J.

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