The effects of eluent mixing on TLS detection in gradient elution HPLC
✍ Scribed by Jasmina Logar; Mateja Šikovec; Alenka Malej; Mladen Franko
- Book ID
- 105887794
- Publisher
- Springer
- Year
- 2002
- Tongue
- English
- Weight
- 281 KB
- Volume
- 374
- Category
- Article
- ISSN
- 1618-2650
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The effectiveness of several basic compounds for testing silica‐based stationary phases was reviewed by applying them to recent columns for reversed‐phase HPLC. Most octadecylsilylated (C18) stationary phases, prepared as a base‐deactivated material from high‐purity silica gel with endc
The inversion of stereochemistry around the nitrogen atom carrying lone pair electrons, by flipping over of sp 3 orbitals, can also be restricted, if alkyl chains surrounding the basic solute in the stationary phase possess low mobility.
## Abstract The combined effect of temperature, __T__, and organic modifier concentration, φ, on the retention under gradient conditions in RPLC is studied by considering, both theoretically and experimentally gradients, of φ at constant __T__ and gradients of __T__ at constant φ. Two approaches ar