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The effects of electronic coupling and solvent broadening on the intervalent electron transfer of a centrosymmetric mixed-valence complex

โœ Scribed by David F Watson; Andrew B Bocarsly


Book ID
111713995
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
186 KB
Volume
211
Category
Article
ISSN
0010-8545

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The Marcus continuum mode1 for the solvent reorientation contribution to the energetics of outer-sphere electron transfer has often been used to analyze the energy of the intervalence transfer (IT) electronic absorption band for a binuclear mixed-valence transition-metal complex. Eel,, the energy re