Electronic structure in the intervalence transfer absorption band of a mixed-valence dimer
โ Scribed by Kober, Edward M.; Goldsby, Kenneth A.; Narayana, D. N. S.; Meyer, Thomas J.
- Book ID
- 126162944
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 904 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
A three-site model for bridged tied-valence dimersis discussed. Adiabatic potential energy surfaces which depend upon the vibrational sum and difference coordinates are obtained. Intensities of the vibronic transitions which contribute to the intervalence transfer band shape are calculated using pop
The Marcus continuum mode1 for the solvent reorientation contribution to the energetics of outer-sphere electron transfer has often been used to analyze the energy of the intervalence transfer (IT) electronic absorption band for a binuclear mixed-valence transition-metal complex. Eel,, the energy re