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Line shape of the intervalence transfer band in bridged mixed-valence dimers: the delocalized case

โœ Scribed by Ko, Jaeju; Ondrechen, Mary Jo


Book ID
127204117
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
917 KB
Volume
107
Category
Article
ISSN
0002-7863

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A model for the intervalence transfer ba
โœ Jaeju Ko; Mary Jo Ondrechen ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 498 KB

A three-site model for bridged tied-valence dimersis discussed. Adiabatic potential energy surfaces which depend upon the vibrational sum and difference coordinates are obtained. Intensities of the vibronic transitions which contribute to the intervalence transfer band shape are calculated using pop