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The Effects of Deuterium Substitution on the Rates of Organic Reactions. X. The Solvolyses of 4-Chloro-4-methyl-2-pentyne and Its Deuterated Analogs

✍ Scribed by Shiner, V. J.; Kriz, George S.


Book ID
126004552
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
418 KB
Volume
86
Category
Article
ISSN
0002-7863

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## Abstract The solvent effect on a nucleophilic substitution reaction of 2‐ and 4‐chloro‐3,5‐dinitrobenzotrifluoride with substituted anilines was studied in methanol, acetonitrile, and toluene at 25Β°C. This reaction is of second order, except 2‐chloro‐3,5‐dinitrobenzotrifluoride in toluene shows