## Abstract The property of environmental stress cracking is a critical performance factor in the polyethylene product areas of rigid and flexible containers, wire and cable insulation and pipe or conduit. It has been known for quite some time that the addition of an elastomeric material to polyeth
The effects of degree of crosslinking on the fatigue crack initiation and propagation resistance of orthopedic-grade polyethylene
β Scribed by Baker, D. A. ;Bellare, A. ;Pruitt, L.
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 412 KB
- Volume
- 66A
- Category
- Article
- ISSN
- 0021-9304
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β¦ Synopsis
Abstract
Crosslinked ultrahigh molecular weight polyethylene (UHMWPE) has been recently approved by the Food and Drug Administration for use in orthopedic implants. The majority of commercially available UHMWPE orthopedic components are crosslinked using eβbeam or gamma radiation. The level of crosslinking is controlled with radiation dose and free radicals are eliminated through heat treatments to prevent longβterm degradation associated with chain scission or oxidation mechanisms. Laboratory studies have demonstrated a substantial improvement in the wear resistance of crosslinked UHMWPE. However, a concern about the resistance to fatigue damage remains in the clinical community, especially for tibial components that sustain high cyclic contact stresses. The objective of this study was to investigate both the initiation and propagation aspects of fatigue cracks in radiation crosslinked medicalβgrade UHMWPE. This work evaluated three levels of radiation, which induced three crosslink densities, on the fatigue crack propagation and total fatigue life behavior. Both asβreceived UHMWPE, as well as those that underwent an identical thermal history as the crosslinked UHMWPE were used as controls. Fractured crack propagation specimens were examined using scanning electron microscopy to elucidate fatigue fracture mechanisms. The results of this work indicated that a low crosslink density may optimize the fatigue resistance from both a crack initiation and propagation standpoint. Β© 2003 Wiley Periodicals, Inc. J Biomed Mater Res 66A: 146β154, 2003
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