The effectivity of solvents as hydrogen bond donors
โ Scribed by Y. Marcus
- Publisher
- Springer US
- Year
- 1992
- Tongue
- English
- Weight
- 29 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0095-9782
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The effect of temperature on the Dimroth-Reichardt ET(30) parameter of binary mixtures of dimethyl sulfoxide, acetonitrile and nitromethane with alcohols and water was studied. The ET(30) polarity parameter of many of these binary mixtures exhibits a strong synergism. Dimethyl sulfoxide, acetonitril
Dimerization energies, ED, internuclear separations, R, and directionality angles have been obtained for the electron donor substituted hydrogen bonds, HO-H\*\*+OHX, X=H, CH3, NH2, OH, and F, from ab initio -molecular orbital calculations with the 4-31G basis. The internuclear separations and direct