The Effect of Zinc Addition on the Oxidation State of Cobalt in Co/ZrO2 Catalysts
β Scribed by Dr. Vanessa M. Lebarbier; Dr. Ayman M. Karim; Dr. Mark H. Engelhard; Dr. Yu Wu; Prof. Bo-Qing Xu; Eric J. Petersen; Prof. Abhaya K. Datye; Prof. Yong Wang
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2011
- Tongue
- English
- Weight
- 350 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1864-5631
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Both CoO and overlayers have been deposited on by evaporation from metallic Co and subsequent Co 3 O 4 SiO 2 oxidation with oxygen and a plasma of oxygen. The combined use of ion scattering spectroscopy and XPS shows that both oxides grow in the form of small particles on the surface of Ion scatteri
## Abstract Sequential addition of CO molecules to cationic arylβhydrido Rh^III^ complexes of phosphineβbased (PCP) pincer ligands was found to lead first to Cο£ΏH reductive elimination and then to Cο£ΏH oxidative addition, thereby demonstrating a dual role of CO. DFT calculations indicate that the oxi