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The effect of trimethylsilyl substituents on the ring-slippage of bis-indenyl-molybdenocene derivatives

✍ Scribed by Isabel S. Gonçalves; Paulo Ribeiro-Claro; Carlos C. Romão; Beatriz Royo; Zara M. Tavares


Book ID
118532339
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
224 KB
Volume
648
Category
Article
ISSN
0022-328X

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Recent studies have shown that the monohqto indenyl compounds (I) of a number of main group and transition series metals exhibit dynanic intramolecular (fluxional) rearrangements.' In the case of the indenylsilanes (Ia) a kinetically slower hydrogen migration occurs, giving rise to non-fluxional pos