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The effect of temperature, conversion and solvent on the stereospecificity of the free radical polymerization of methyl methacrylate

✍ Scribed by T.G. Fox; H.W. Schnecko


Publisher
Elsevier Science
Year
1962
Tongue
English
Weight
548 KB
Volume
3
Category
Article
ISSN
0032-3861

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The effect of LiClO 4 on the polymerization of methyl methacrylate (MMA) with dimethyl 2,2-azobisisobutyrate (MAIB) was investigated at 50ЊC in methyl ethyl ketone. The polymerization proceeded homogeneously even at [LiClO 4 ] as high as 3.00 mol/L. The polymerization rate (R p ) and the molecular w