The kinetics of free radical homopolymerization of methyl methacrylate in the presence of n-dodecyl mercaptan have been studied at 70 in bulk, using a 3 mol/1 solution in benzene. The results indicate that, when the polymerization is carried out in solution, the chain transfer agent does not influen
The effect of temperature, conversion and solvent on the stereospecificity of the free radical polymerization of methyl methacrylate
β Scribed by T.G. Fox; H.W. Schnecko
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- English
- Weight
- 548 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0032-3861
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## Abstract A model is proposed for the radicalβinduced polymerization of methyl methacrylate which combines concepts given in the literature. Consecutive steps for diffusion and reaction are used for both the propagation and the termination process, and the termination at higher degrees of convers
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