The effect of sulfur and selenium substitutents on the regiochemistry of diels-alder reactions
β Scribed by Charles L. Liotta; John W. Verbicky Jr.
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 191 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The activation and reaction volumes (βV /βV) were showing negative volumes of activation (βV Ο½ 0) whereas the others are slightly retarded (βV ΟΎ 0). From the analysis determined for the retro Diels-Alder reactions of the parent dihydrobarrelene 1a, its 2-cyano derivative 1b, the exo and of the volum
L'w:~ 1111' MINDO/3 msthod, variation of thr potential barrier for the Dick-Alder rcaclion between I-hydroxybutadicnc .md s~ralsin, cJtA?'zcd b? BF3 and NH:. hJs been studied. An interpretaGon of the experimental facts about the inrrc.tsc of rqIosrlrcIiviry and stereo~ciccti~ it\ for Dick-Alder rext
Hetero Diels-Alder reactions / Enamino ketones 1 High-pressure reactions / Pyrans The hetero Diels-Alder reaction of enamino ketone 1 with the vinyl ethers 7-11 leading to the dihydropyrans 12a-e and 13ae is studied in dichloromethane under high pressures up to 7 kbar. The kinetics is measured by o