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The Effect of Solvent on the Pinacol Rearrangement of cis- and trans-1,2-Diphenyl-1,2-Acenaphthenediols. I. Methyl and Ethyl Alcohols 1,2

✍ Scribed by Brown, Ronald F.


Book ID
121457807
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
546 KB
Volume
74
Category
Article
ISSN
0002-7863

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Rearrangement of 1,2-divinyl-1,2-cyclohexanediol (I) was shown by Coda, et al (1) to give l-bicyclo[5.3.O]decen-2-one (II). We had made the ssme observation independently (2), but had also found that under milder conditions 7-hydroxybicyclo[5.3,0] decsn-2-one (III) can be isolated in good yield. In