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The effect of small substituents on the properties of indole. An ab initio 6-31G* study

✍ Scribed by Giuliano Alagona; Caterina Ghio; Susanna Monti

Book ID
114142966
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
372 KB
Volume
433
Category
Article
ISSN
0166-1280

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## Abstract The electrocyclization of 4‐substituted 3‐silyloxy‐2‐azadienes to β‐lactams was studied at the MP2/6‐31G\* level of theory and the effect of the substituents on the reactivity of the azadiene and on the stereochemistry of the cyclic products was evaluated. It was shown that the electroc