The effect of polydispersity on rotational diffusivity and shear viscosity of rodlike polymers in concentrated solutions
β Scribed by G. Marrucci; N. Grizzuti
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1983
- Tongue
- English
- Weight
- 167 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0887-6258
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π SIMILAR VOLUMES
## Abstract The model of Doi for the rotational dynamics of rodlike molecules in solution is compared with that of Warchol and Vaughan and Wang and Pecora. The similarities in the results for dielectric relaxation are discussed and the application of the models to the behaviour of isotropic solutio
## Abstract The earlier calculations of Moscicki and Williams of the phase behavior of rodlike macromolecules in solution incorporating a Gaussian distribution of rod lengths have been extended to include, in addition to a βbasicβ Gaussian distribution, a small amount of highβmolecularβweight speci
A, is partitioned as shown by the cross hatching and modified to produce the second base case A, of Figure 6. The cycle is now pseudo node a indicated in Figure 4. Operations are continued up to k ' when another cycle is located consisting of nodes 9, 10, 12, and pseudo node a. A? is partitioned an
The effects of high-shear processing and thermal exposure on the molecular weight and solution viscosity stability of selected polymers were studied. Aqueous solutions of two molecular weight grades of hydroxyethyl cellulose (HEC) were subjected to high-shear rates using a high-shear mixer and two c