The effect of neutral molecule vibrational energy content in molecular H2+-H2 charge-transfer reactions
β Scribed by M.R. Flannery; J.V. Hornstein; T.F. Moran
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 366 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The CIOSS sections far Hz-Hz charge-transfer reactions of nC~stiionall~ excited neutrzl target molecules have been computed as a fundi0n cf kimtic erergy ushg a multistate impact parameter trestment T!w cross sections illVOLVblg ViirU.iOIlally excited neutmls are &nikmtly larger than those involving ground state re;lckn?s.
In the model&ng of high temperature plasmas it is the electron energy [7,8]. H&ever; crossed beam eximportant to have knowledge of the flux and distribu-perimenrs in which the neutral target vibrational state tion of hot neutral particles entering and leaving the plasma volume. The velocity distribution functio& of is varied are difficult to perform and charge-transfer CIOSS sections involving exciteci neutraf reactants have fast neutraiS [l] in the plasma is dependent on the '
π SIMILAR VOLUMES
Reaction and charge transfer of Hb c Ar to give ArH+ and Ar+ have been mvestigated as a function of H; vibrational quantum state and kinetic energy (Ecmm\_). usmg photomnizatron and gurded beam ran optics. Resonance effects are important in charge transfer, proton and charge transfer are closely cou
A crossed beam study of the title reaction if reported, from 0.45 to 7.8 eV. The reaction is predominantly transkxtioionally endothermic. At the lowest energy, there is evidence for two reactlon paths: a long-range electron transfer and an titimate coihsion mth electron transfer. Branching ratios fo
A three-dimensional quantum-mechanical study of the (Ar + Hz)+ system within the reactive infinite-order sudden approximation is presented. All four possible channels for chemical reaction and charge transfer were treated simultaneously. The various cross sections deviate by at most 50% from recent