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The effect of low pressure on a high-spin—low-spin transition

✍ Scribed by E. Meissner; H. Köppen; H. Spiering; P. Gütlich

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
358 KB
Volume
95
Category
Article
ISSN
0009-2614

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✦ Synopsis

Theeffect oflow pressure @= 150 bar) on the high-spin (HS)-lowrpin (LS) transition in [Fe_,Znl__~(2-pic)~] Cl,-E1OH (x = OS, 1.0) was measured by Mkbauer spectroscopy and the results compared with theory. The linear dependence of the volume of the lattice on the HS fraction, which is the basic assumption of the theory, was proven by temperaturedependent X-ray measurements.

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