Dedicated to Professor Michele Parrinello on the occasion of his 60th birthday.
The effect of hydrogen bonding on the bond lengths and angles in the carboxyl group
โ Scribed by Mizuhiko Ichikawa
- Publisher
- Springer
- Year
- 1979
- Tongue
- English
- Weight
- 850 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1572-8854
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
THE discovery that the C13-H nuclear spin-spin coupling constant appears to be a linear function of the amount of s-character in the carbon orbital from which a C-H bond is formed1 has made direct estimation of hybridization possible for the first time. In cyclopropanela and certain cyclopropenes2 t
Proton (deuteron) transfer ofhydrogen bonds in benzoic, glutark and pformylbenzoic acids was studied by proton (deuteron) T, measurements. Deuteration of carboxylic protons was found to increase the barriers to classical proton jumping as well as quantum-mechanical tunneling. The former barriers inc