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Hydrogen bonding and the ultrafast time response in carboxylic acids

✍ Scribed by V Crupi; S Magazu'; G Maisano; D Majolino; P Migliardo; A.M Musolino


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
467 KB
Volume
381
Category
Article
ISSN
0022-2860

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A study of hydrogen-bond dynamics in car
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Proton (deuteron) transfer ofhydrogen bonds in benzoic, glutark and pformylbenzoic acids was studied by proton (deuteron) T, measurements. Deuteration of carboxylic protons was found to increase the barriers to classical proton jumping as well as quantum-mechanical tunneling. The former barriers inc