𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The effect of high magnetic fields on the vapour pressures of nitrogen, oxygen and argon

✍ Scribed by A.J. Meachin; M.W. Biddulph


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
282 KB
Volume
18
Category
Article
ISSN
0011-2275

No coin nor oath required. For personal study only.

✦ Synopsis


Equatrons are derived/or predrcting the change m the vapour pressure curves o/oxygen, nitrogen and argon m the presence ol h~gh magnetrc fields. The G~bbs energies of the vapour and hquid phases are equated, thus producing a 'magnetic Clausius Clapeyrnn' equatton. The theoretical results are compared with experimental data measured at helds up to 9.5 x I06 Am ~, using a specially desrgned cryostat and sample holder.

It was found that the effects on the vapour pressure curves o/ mtrogen and argon were insignificant at any field strength. For oxygen, the effect was small and only accurately measureable at very htgh helds. The agreement between the theoretical and practical results was good.

An effect on the vapour hqutd equilibrium curve tor mtrogen oxygen mtxtures predtcted by prevrous author.% 2 by wrtue o/ an effect on the vapour pressures of the pure comp onents, /s unhkely to occur. -d] )'O " " arid .~meΒ’ O'N z ~)z -FNz'TN,/F().Tq)., this Β’tlanp~ was calculalc'd I,,;mth~ chan[.;e m P~,'/~,~ (,e the latio ul the v;.Ipuuf prc's~ures ul Ihe pure c,~mpunenls) with I~eld. 'T'hJs melhud huweve= dues not a~.'~.'uunl I'(, any chang, e m the


πŸ“œ SIMILAR VOLUMES


Magnetic field effects on the gas-phase
✍ V.I. Makarov πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 367 KB

Magnetic field effects on the NO2 photolysis rate at an energy range below the dissociation threshold are shown to be identical to those observed in fluorescence. According to the data obtained, both the 'B2 and \*B, states of NO2 are reactive. The high pressure data have been explained in terms of