The effect of high magnetic fields on the vapour pressures of nitrogen, oxygen and argon
β Scribed by A.J. Meachin; M.W. Biddulph
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 282 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0011-2275
No coin nor oath required. For personal study only.
β¦ Synopsis
Equatrons are derived/or predrcting the change m the vapour pressure curves o/oxygen, nitrogen and argon m the presence ol h~gh magnetrc fields. The G~bbs energies of the vapour and hquid phases are equated, thus producing a 'magnetic Clausius Clapeyrnn' equatton. The theoretical results are compared with experimental data measured at helds up to 9.5 x I06 Am ~, using a specially desrgned cryostat and sample holder.
It was found that the effects on the vapour pressure curves o/ mtrogen and argon were insignificant at any field strength. For oxygen, the effect was small and only accurately measureable at very htgh helds. The agreement between the theoretical and practical results was good.
An effect on the vapour hqutd equilibrium curve tor mtrogen oxygen mtxtures predtcted by prevrous author.% 2 by wrtue o/ an effect on the vapour pressures of the pure comp onents, /s unhkely to occur. -d] )'O " " arid .~meΒ’ O'N z ~)z -FNz'TN,/F().Tq)., this Β’tlanp~ was calculalc'd I,,;mth~ chan[.;e m P~,'/~,~ (,e the latio ul the v;.Ipuuf prc's~ures ul Ihe pure c,~mpunenls) with I~eld. 'T'hJs melhud huweve= dues not a~.'~.'uunl I'(, any chang, e m the
π SIMILAR VOLUMES
Magnetic field effects on the NO2 photolysis rate at an energy range below the dissociation threshold are shown to be identical to those observed in fluorescence. According to the data obtained, both the 'B2 and \*B, states of NO2 are reactive. The high pressure data have been explained in terms of