✦ LIBER ✦

Magnetic field effects on the gas-phase photolysis of nitrogen dioxide: Pressure dependence of the photolysis rate

✍ Scribed by V.I. Makarov

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 367 KB
Volume: 148
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87285-3

No coin nor oath required. For personal study only.

✦ Synopsis

Magnetic field effects on the NO2 photolysis rate at an energy range below the dissociation threshold are shown to be identical to those observed in fluorescence. According to the data obtained, both the 'B2 and *B, states of NO2 are reactive. The high pressure data have been explained in terms of an excited collision complex (NO*):, which is efficiently quenched by collisions.

IntIoductloa

📜 SIMILAR VOLUMES

Magnetic field dependence of the product

Magnetic field dependence of the product yields of cycloheptanone photolysis in the dilute gas phase

✍ E.M. Stich; W.F. Baumeister; J.Robert Huber 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 574 KB

The pressure-dependence of fluorescence

The pressure-dependence of fluorescence intensity and photolysis rate of the vapors of carbon bisulfide, nitrogen dioxide, and sulfur dioxide

✍ V. I. Makarov 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 819 KB

This article is concerned with the Stern-Volmer dependence on the NOz, SOz, and CS2 fluorescence self-quenching within a wide range of pressure variations of these gases. Besides, the pressure-dependences of the photolysis rate of these substances have been investigated. The deviations from linearit

The external magnetic field effect on th

The external magnetic field effect on the singlet sensitized photolysis of dibenzoyl peroxide

✍ Y. Tanimoto; H. Hayashi; S. Nagakura; H. Sakuragi; K. Tokumaru 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 324 KB

The influence of a magnetic field on the

The influence of a magnetic field on the fluorescence and photolysis rate of carbon disulfide vapour

✍ V.I. Makarov; N.M. Bazhin 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 441 KB

The effect of a magnetic field on the fluorescence of carbon disulphide vapour under stationary excitation by light with A = 313Ok 30 A has been investigated at 0.014-165.1 Torr. Over the whole range of pressure, the magnetic effect does not depend on the gas pressure. A magnetic field has been foun

Influence of magnetic field on the cage

Influence of magnetic field on the cage effect during photolysis of p-benzoquinone in n-propanol

✍ I.V. Khudyakov; A.I. Prokof'ev; L.A. Margulis; V.A. Kuzmin 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 335 KB

The effect of a magnetic field on the escape of alkoxyl radicals from the solvent ca8e in n-propanol at 213 I< has been investigated. The alkoxyl radicals were obtained by photooxidation of n-propanol with the aid of p-beruoquinone m the triplet state. The radicals that escaped from the cage were tr

The effect of high magnetic fields on th

The effect of high magnetic fields on the vapour pressures of nitrogen, oxygen and argon

✍ A.J. Meachin; M.W. Biddulph 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 282 KB

Equatrons are derived/or predrcting the change m the vapour pressure curves o/oxygen, nitrogen and argon m the presence ol h~gh magnetrc fields. The G~bbs energies of the vapour and hquid phases are equated, thus producing a 'magnetic Clausius Clapeyrnn' equatton. The theoretical results are compare