## Abstract The particle nucleation mechanism in emulsion polymerization of styrene with a novel polyester emulsifier, 5βsulfoisophthalic acid dimethyl ester sodium saltβmodified tetracarboxylic acidβterminated polyester (SMTAPE), was investigated. The consumption of SMTAPE micelles was monitored b
The effect of emulsifier-polymer complex formation on particle nucleation in emulsion polymerization
β Scribed by W. A. B. Donners
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1987
- Tongue
- English
- Weight
- 728 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0887-6258
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π SIMILAR VOLUMES
The formation of oligomers in emulsifier-free emulsion polymerization of styrene was characterized by means of gel permeation chromatography and surface tension measurements. GPC analysis showed incessant oligomer formation throughout the emulsion polymerization process. Oligomers spanned a molecula
## Abstract Seeded emulsion polymerizations of vinyl acetate with and without poly(vinyl alcohol) were carried out in a batch reactor. Two types of poly(vinyl alcohol) (different molecular weights but the same degree of hydrolysis) have been investigated. In the absence of poly(vinyl alcohol) no ne
The emulsifier-free emulsion polymerization of vinyl acetate was carried out in the absence or in the presence of some electrolytes such as sodium chloride, calcium chloride, aluminum chloride, sodium sulphate, and ammonium phosphate at 50ΠC using potassium persulphate-sodium bisulphite as a redox i