The kinetics of emulsifier-free emulsion polymerization of vinyl acetate using the redox initiation system of potassium persulfate-potassium metabisulfite was studied. The effect of the reaction conditions on the rate of polymerization was also investigated. The polymerization proceeded smoothly unt
Effect of electrolyte on the emulsifier-free emulsion polymerization of vinyl acetate
β Scribed by A. B. Moustafa; A. A. Abdel-Hakim; S. M. Sayyah; G. A. Mohamed
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 156 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
The emulsifier-free emulsion polymerization of vinyl acetate was carried out in the absence or in the presence of some electrolytes such as sodium chloride, calcium chloride, aluminum chloride, sodium sulphate, and ammonium phosphate at 50ΠC using potassium persulphate-sodium bisulphite as a redox initiation system. The viscosity average molecular weights of the polymers obtained were also determined.
π SIMILAR VOLUMES
Three di β erent emulsiΓer types from vinyl acetate monomer and methoxypolyoxyethylene (35 : 65, 27 : 73 and 19 : 81 wt : wt%) were prepared in the presence of benzoyl peroxide using a macroradical initiator technique. Fourier transform infrared spectroscopy and 1H nuclear magnetic resonance were car
## Abstract Polystyrene/poly(vinyl acetate) latex nanoparticles with a coreβshell morphology in an emulsifierβfree emulsion polymerization system were prepared with purified styrene and vinyl acetate (VAc) as monomers and 2,2β²βazo bis(2βamino propane) dihydrochloride (ABA,2HCl) as the initiator and