The effect of dimerization on the resonance raman excitation profiles of metalloporphyrins
โ Scribed by M.Z. Zgierski
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 610 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
It IS shown that dramahc charges m excxtation profiles of certain fundamentals of Pt-phthalocyanine upon mking the achloronaphthakne solvent with n-octane, can be rationaked in terms of a solventdependent co&&ration interaction strength between the B and Q electromc states of a solute molecule.
Novel features in the resonance Raman spectra of metalloporphyrins are predicted to ensue via the recently revealed crossquadralic nuclear potential terms involving modes of different symmetry\_ Such terms were shown to prevail in the doubly degenerate excited electronic states corresponding to the
The unique amplitude obtained by an inversion of an observed Raman excitation profile is one of minimal phase. As the frequency varies, the phase of such an amplitude can span a range larger than 27r. Therefore such an inversion can yield an amplitude that accurately reproduces the input profile. It
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