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Solvent effects on resonance raman excitation profiles of platinum phthalocyanine

✍ Scribed by M. Pawlikowski; M.Z. Zgierski

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
247 KB
Volume
74
Category
Article
ISSN
0009-2614

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✦ Synopsis

It IS shown that dramahc charges m excxtation profiles of certain fundamentals of Pt-phthalocyanine upon mking the achloronaphthakne solvent with n-octane, can be rationaked in terms of a solventdependent co&&ration interaction strength between the B and Q electromc states of a solute molecule.

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## Abstract The effect of static inhomogeneous environmental broadening of resonance Raman excitation profiles was investigated. The roles of diagonal and non‐diagonal terms in the two‐fold sum over the local mode vibrational states in the excited intermediate electronic state are discussed. The th