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The effect of Cl(I)− ions on kinetics and mechanism of anodic dissolution and cathodic deposition of copper

✍ Scribed by Zvonimir D. Stanković

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
290 KB
Volume
29
Category
Article
ISSN
0013-4686

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✦ Synopsis

The influence of Cl(I)-ions on kinetics and mechanism of anodic dissolution and cathodic deposition of copper in acidic sulfate system was investigated. For this investigation the galvanostatic singlepulse method has been used. The results indicate that Cl(I) -ions change the exchange current density and transfer coefficients as determined from tafel analyses of the anodic and cathodic reactions.

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✍ A.B. Delgado; D. Posadas; A.J. Arvia 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 820 KB

The anodic dissolution of nickel in HCl-DMSO solutions containing different supporting electrolytes has been studied between 2@45"C. The electrodissolution and electrodeposition are predominantly activated electrode processes. At high anodic potentials and in the presence of perchlorate ions at high