Akaret -The influence of bromide ions on the kinetics and mechanism of anodic dissolution of cadmium in methanol, NJJdimetbylformamide and acetonitrile has beca investigated. The experimental results indicate the direct participation of Br-ions in the examined reaction.
Kinetics and mechanism of cadmium anodic dissolution in organic solvents - I
β Scribed by S. Biallozor
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 333 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The anodic dissolution of nickel in HCl-DMSO solutions containing different supporting electrolytes has been studied between 2@45"C. The electrodissolution and electrodeposition are predominantly activated electrode processes. At high anodic potentials and in the presence of perchlorate ions at high
A technique is described which permits a recording of mechano-electrochemical dissolution current at constant pre-determined strain rates for the Culaq. CuSO, system under potentiostatic control. Studies have been carried out in the range 2-5-l 5 mV with strain rate ranging from 0447 to O-9105 strai
The anodic behaviour of Cd and Fe in chloride, nitrate and per&orate solutions in AN and DMF have been investigated. The experimental values of the corrosion potential and Tafel slopes have been obtained. The direct participation of anions in the anodic reactions is stated. The possible schemes of t
The interfacial energies between m-acetotoluide and four saturated hydrocarbon solvents, n-hexane, n-heptane, cyclohexane, and decahydronaphthalene, were determined using the Ostwald-Fruendlich equation. Dissolution rates were determined in a descending direction to obtain interfacial control. The d
The influence of Cl(I)-ions on kinetics and mechanism of anodic dissolution and cathodic deposition of copper in acidic sulfate system was investigated. For this investigation the galvanostatic singlepulse method has been used. The results indicate that Cl(I) -ions change the exchange current densit