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The effect of chloride doping on the crystal structure of the mixed-valence linear chain [Pten2][Pten2Br2](ClO4)4

โœ Scribed by Huckett, Sara C.; Garcia, Ed; Laia, J.R.; Caroll, D.; Swanson, Basil I.


Book ID
123511075
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
162 KB
Volume
42
Category
Article
ISSN
0379-6779

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Calculations of the resonance Raman excitation profiles for the v, band and its overtones have been performed for the linearchain mixed-valence platinum complex [Pt(en)\*] [Pt(en)zBr,]Br, It is found that the Pt'"-Br bond length increases by 0.075 A in the intervalence state. A satisfactory fit to t