Ionization of the Ni 3s core level in NiO has been studied using ab initio wavefunctions for an Ni06 cluster model. Three important fmal state effects are studied: (1) ligand to Ni 3d charge transfer, (2) exchange coupling of the ionized core level within the open 3d shell; and (3) atomic correlatio
The effect of chemisorption on substrate core levels observed by XPS
β Scribed by J.C. Fuggle; D. Menzel
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 386 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
core level peaks from ruthenium and tungten have been found to shifr to higher biading energies by up to 0.3 eV upon oxygen chemisorption.
This effect has been Investigated as a function of oxygen coverage and electron emission angle.
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