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The effect of chemical structure of derivatives of 1,1-bis(4-hydroxyphenyl)-2,2-propane on the antiplasticization of polycarbonate

✍ Scribed by Leszek Makaruk; Hanna Polańska; Tadeusz Mizerski

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
441 KB
Volume
23
Category
Article
ISSN
0021-8995

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✦ Synopsis

Abstract

The antiplasticizing effect of ester derivatives of bisphenol A: 1,1‐bis(4‐hydroxyphenyl)‐2,2‐propane diacetate (DAPP), 1,1‐bis(4‐hydroxy‐3,5‐dichlorophenyl)‐2,2‐propane diacetate (DACPP), 1,1‐bis(4‐hydroxy‐3,5‐dibromophenyl)‐2,2‐propane diacetate (DABPP), 1,1‐bis(4‐hydroxy‐3,5‐dichlorophenyl)‐2,2‐propane dibenzoate (DBCPP), 1,1‐bis(4‐hydroxy‐3,5‐dichlorophenyl)‐2,2‐propane di‐2,4‐dichlorobenzoate (DCBCPP) on polycarbonate was investigated. Obtained results indicate that antiplasticizing abilities of these compounds depend on the number of polar groups in the molecule, as well as on the possibility of tight filling the free volume by the molecules in polymer–antiplasticizer system.

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