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The Effect of Certain Peroxides and Acids on the Reduction of Olefins in Alcohol Solution with Platinum Oxide Catalyst

✍ Scribed by Thomson, George


Book ID
127337844
Publisher
American Chemical Society
Year
1934
Tongue
English
Weight
418 KB
Volume
56
Category
Article
ISSN
0002-7863

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Mntrimethyltriazacyclononane/ascorbic a
✍ Albrecht Berkessel; Christoph A. Sklorz 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 253 KB

The system comprised of manganese(II) acetate or sulfate, 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) and ascorbic acid efficiently catalyzes the epoxidation of olefins and the oxidation of alcohols with hydrogen peroxide. For example, in the presence of as little as 0.03 mol% of Mn 2÷, methyl