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Solvent Effects during the Oxidation of Olefins and Alcohols with Hydrogen Peroxide on Ti-Beta Catalyst: The Influence of the Hydrophilicity–Hydrophobicity of the Zeolite

✍ Scribed by A. Corma; P. Esteve; A. Martı́nez


Book ID
112254553
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
256 KB
Volume
161
Category
Article
ISSN
0021-9517

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Mntrimethyltriazacyclononane/ascorbic a
✍ Albrecht Berkessel; Christoph A. Sklorz 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 253 KB

The system comprised of manganese(II) acetate or sulfate, 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) and ascorbic acid efficiently catalyzes the epoxidation of olefins and the oxidation of alcohols with hydrogen peroxide. For example, in the presence of as little as 0.03 mol% of Mn 2÷, methyl