𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The effect of catalytic reaction conditions on the incorporation of tritium in unsaturated compounds

✍ Scribed by V. P. Shevchenko; I. Yu. Nagayev; N. F. Myasoedov

Publisher
John Wiley and Sons
Year
1989
Tongue
French
Weight
736 KB
Volume
27
Category
Article
ISSN
0022-2135

No coin nor oath required. For personal study only.

✦ Synopsis

We have obtained multiple-tritium-labelled 5-d-androstan-

-butyl-p-coumaric acid and dihydrofusicoccin. By varying the conditions for the hydrogenation of terminal double bonds one can considerably increase the molar radioactivity of such compounds through isotopic exchange. We discuss some tentative explanations of the effect of the labelling reaction conditions upon the synthesis of compounds with desired properties.

πŸ“œ SIMILAR VOLUMES

Tritium incorporation into solvents unde
Tritium incorporation into solvents under the conditions of catalytic dehalogenation
✍ B. ČernΓ½; J. HanuΕ‘ πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 French βš– 256 KB

## Abstract Incorporation of tritium into selected polar solvents was studied in the presence of bases and buffering substances. Tritium gas was used as a tritium source and the, reaction was catalyzed by PdO, Pd/BaSO~4~, Raney nickel.

The tritium incorporation into the solve
The tritium incorporation into the solvents under conditions of catalytic hydrogenation
✍ J. Hanus; B. Cerny; J. Benes πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 French βš– 251 KB

## Abstract The incorporation of tritium gas into dioxan, tetrahydrofuran, ethyl acetate, dimethylformamide, dimethylacetamide, dimethylsulfoxide and acetic acid anhydride was studied in the presence of heterogeneous catalysts PdO (Adams), PtO~2~ (Adams), Pd/BaSO~4~ (10%). For the solvents and cata

Effect of solvent polarity on the rate o
Effect of solvent polarity on the rate of ozone reaction with unsaturated compounds
✍ M. Gomes; S. D. Razumovskii; G. E. Zaikov πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 English βš– 202 KB πŸ‘ 1 views

The effect of the polarity of seven solvents (c = 2-60) on the rate of ozone reactions with stilbene and ally1 chloride has been studied. The data show that the rate of the reaction is insensitive to the medium polarity. The results of earlier publications are revised and are shown to be in agreemen