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The Effect of Benzo Substitution on Complexation of Diaza 18-Crown-6 Ethers Derivatives with NaClO4

✍ Scribed by M.Zafer Köylü; Nadir Demirel; F.Doganel Polat; Ali Yılmaz; Halil Hoşgören; Metin Balci

Publisher
Springer Netherlands
Year
2006
Tongue
English
Weight
148 KB
Volume
56
Category
Article
ISSN
0923-0750

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13C NMR relaxation time measurements of
13C NMR relaxation time measurements of macrocyclic ether complexes. The association of benzo[18]crown-6 with NaClO4·H2O in acetonitrile
✍ Çakıl Erk; Manfred D Zeidler 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 406 KB

Association constants for the complex Na'/benzo [18]crown-6 in acetonitrile solution were determined from t3C-NMR relaxation time measurements at different temperatures. The dipolar contributions to relaxation were separated by nuclear Overhauser enhancement measurements. The contributions are split