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Solvent effects on complexation of crown ethers with LiClO4, NaClO4and KClO4in methanol and acetonitrile

✍ Scribed by Alessandro D'Aprano; Mark Salomon; Vincenzo Mauro


Publisher
Springer US
Year
1995
Tongue
English
Weight
923 KB
Volume
24
Category
Article
ISSN
0095-9782

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✍ Çakıl Erk; Manfred D Zeidler 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 406 KB

Association constants for the complex Na'/benzo [18]crown-6 in acetonitrile solution were determined from t3C-NMR relaxation time measurements at different temperatures. The dipolar contributions to relaxation were separated by nuclear Overhauser enhancement measurements. The contributions are split