The effect of anharmonicity on the vibrational relaxation of matrix-isolated small molecules
โ Scribed by Adam Cenian; Helmut Gabriel
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 980 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Recent experimental tnvesttgatrons of the popufar~on evofutron of the vibrational states of CO dduted in Ar indtcatc Ihat the rates of tbc reactions CO( 1) + CO(u) -CO(O) + CO(u + 1) \* ti Increase with u for u = l-3, and that they are approxrmatcly constant for u = 3-5. This surpnsmg and unexp
## Vlbrational-rotatlonal couphng, due to the fact that the center of interaction IS displaced from the center of mass in a heteronuclear diitomrc molecule, provides a mechanism for nonradiatwe vibrational relazxation of diitomic impurities in matrlces. A theoretical expresaon for the rate constan