[1,3] and [3,3] rearrangements of 3-amin
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Heather K. Dobson; Richard LeBlanc; Hélène Perrier; Corey Stephenson; Teresa R.
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Article
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1999
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Elsevier Science
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French
β 223 KB
3-Amino-l,5-Hexadienes rearrange under anionic conditions to give a [1,3] product in addition to the [3,3] (Cope) product. With some substrates the regioselectivity of the reaction is strongly influenced by the solvent polarity.