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The effect of 2-exo and endo substituents on the geometry of norbornane

✍ Scribed by J.Walkimar de M. Carneiro; Peter Rudolf Seidl; José Glauco R. Tostes; C.A. Taft

Book ID: 119116806
Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 476 KB
Volume: 152
Category: Article
ISSN: 0166-1280
DOI: 10.1016/0166-1280(87)80068-4

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## Abstract The solvolysis rates and products of the 6‐__exo__‐substituted 2‐__exo__‐ **1a**‐**1u**, and 2‐__endo__‐norbornyl __p__‐toluenesulfonates **2a**‐**2u**, have been determined. In general, the rate constants for **1** and **2** (log __k__) correlate well with the inductive constants σ of