The dynamic stereochemistry of compounds containing CN bonds
✍ Scribed by W.R. Jackson; W.B. Jennings
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 112 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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The electroreduction mechanism of +haIogen derivatives of organic compounds in proton donating solvents was investigated on the exampie of optically active 2-phenyl-2-chloropropionic acid. It was shcwn that the electroreduction occurs with inversion of configuration according to the SN2 mechanism.
The bond dissociation energies (0,) of C>H>, &Ho, CzHa, Nz, N2H2, and NzH4 are studied at various levels of correlation treatment. The convergence of 0. with respect to the one-particle basis is studied at the single-reference modified coupled-pairfunctional (MCPF) level. At all levels of correlatio