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Stereochemistry of the electroreduction of the CC1 bond

✍ Scribed by Barbara Czochralska

Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
286 KB
Volume
1
Category
Article
ISSN
0009-2614

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✦ Synopsis

The electroreduction mechanism of +haIogen derivatives of organic compounds in proton donating solvents was investigated on the exampie of optically active 2-phenyl-2-chloropropionic acid. It was shcwn that the electroreduction occurs with inversion of configuration according to the SN2 mechanism.

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The CH bond energy of formaldehyde
The CH bond energy of formaldehyde
✍ William E. Palke; Bernard Kirtman 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 279 KB

In order to compare with recent accurate measurements, the carbon-hydrogen bond energy in formaldehyde has been calculated. Both electron correlation and extensively polarized basis sets are required to obtain satisfactory results. The most extensive computation predicts a CH bond energy of 85.4 kca